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Invented Pretty much in precisely the same time as BBO, LBO has the very best hurt threshold, and superior interior crystal excellent than BBO. LBO can reach non-significant phase matching for SHG1064nm about 150C, which as well as its superior injury theshold, will make LBO the best SHG crystal for top electrical power 1064nm devices. DKDP (deuterated KDP), KDP, ADP were the very first commercially readily available NLO crystals . The deserves of DKDP or KDP contain cost-effectiveness and large dimensions availability. For large apertures, like People about 50mm, DKDP, KDP and ADP are the one choices. KNbO3's conversion effectiveness is great. And direct SHG of diode lasers more info has now been claimed. However the multi-domain-challenge is its major disadvantage. LiIO3 has a significant conversion performance, and it is a snap to obtain in big sizes. Although the hygroscopicity and minimal injury threshold Restrict its apps. AgGaS2 and AgGaSe2 are The main NLO crystals in IR ranges, considering the fact that the majority of the earlier mentioned NLO crystals are only transparent in seen or close to-IR vary. The everyday use of both of these crystals are as SHG of CO2 lasers, in addition to OPO crystals to crank out IR or much IR radiations. How are you going to choose the appropriate NLO crystals? Here's the listing of thoughts you have to reply:
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The fundamental optical absorption edges in these LixAg1−xInSe2 compounds are established through the direct
AgGaSe/sub 2/ crystal growth has long been recognized by an improved Bridgman strategy with merely a just one-zone vertical expansion furnace. The approach is to generate the solid-liquid interface go from The underside…
Normally, not all answers to the above thoughts are "Sure", so You must stike a stability between these aspects to discover the finest Option for your personal devices. As an example, to get a SHG crystal for Ti:Sapphire laser at 800nm, with the pulse width of 40fs, plus the predicted pulse broadening outcome a lot less than 20fs. KTP, AgGaSe2 or AgGaS2 cannot obtain stage matching of SHG800nm; LiIO3's damage threshold is just not substantial plenty of; Both equally BBO and KDP are ideal, however, BBO's conversion effieicy is bigger than KDP, and 100micron BBO SHG800nm can only produce pulse broadening result of 19fs.
Premium quality AgGaSe2 one crystals with 20 mm in diameter and 55 mm in duration are already grown by Bridgman strategy. It is actually found that there's a 2nd phase of Ag-abundant Ga2Se3 (or named AgGa7Se11) from the AgGaSe2 crystal.
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Based on the big measurement Li0.81Ag0.19InSe2 single crystals of optical high quality, the spectroscopic Qualities are